They're playing #1 UConn right now on ESPN Full Court (normally a subscription service, but it's free this week). If you have Comcast it's on channel 706.
UConn will probably win this handily, but so far the Orange women are keeping the game within reach. This was a great game last year, so hopefully they'll keep it close this time, too.
Oh, and if you need more reasons to watch, check this out.